1-Ferrocenylmethyl-1H-imidazole

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1-Ferrocenylmeth­yl-1H-imidazole

In the title compound, [Fe(C(5)H(5))(C(9)H(9)N(2))], the distances of the Fe atom from the centroids of the unsubstituted and the substituted cyclo-penta-dienyl (cp) rings are 1.639 (1) and 1.647 (1) Å, respectively. The ferrocenyl unit deviates from an eclipsed geometry with tilted cp rings; the inter-planar angle between the cp and imidazole rings is 114.11 (4)°.

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4-Phenyl-1H-imidazole (a low-temperature redetermination), 1-benzyl-1H-imidazole and 1-mesityl-1H-imidazole.

Low-temperature studies of the simple variously substituted imidazole types 4-phenyl-1H-imidazole, C9H8N2, 1-benzyl-1Himidazole, C10H10N2, and 1-mesityl-1H-imidazole, C12H14N2, extend comparisons between parent imidazole species and their derivatives, the pronounced double-bond localization opposite the substituted N atom common to simple neutral species being redistributed aromatically on prot...

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(S)-1-(1-Ferrocenylmethyl-1H-benz­imidazol-2-yl)ethanol monohydrate

In the structure of the title compound, [Fe(C(5)H(5))(C(15)H(15)N(2)O)]·H(2)O, the unsubstituted cyclo-penta-diene (Cp) ring is disordered over two positions, with site-occupancy factors of 0.636 (12) and 0.364 (12). The dihedral angles between the planes of the substituted Cp ring and the major and minor components of the disordered ring are 0.8 (3) and 3.4 (6)°, respectively. The crystal pack...

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1-(6-Ferrocenylhex­yl)-1H-imidazole

The title compound, [Fe(C(5)H(5))(C(14)H(19)N(2))], is characterized by a ferrocenyl group separated from an imidazole functionality by a straight-chain hexyl unit. The two cyclo-penta-dienyl rings of the ferrocenyl group show a marginal inward tilt of 2.17 (2)°. The imidazole unit, which is essentially planar (with a maximum deviation of 0.007 A for one of the N atoms) and tilted away from the...

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4-Hydroxy­benzoic acid–1H-imidazole (1/1)

In the title 1:1 adduct, C(7)H(6)O(3)·C(3)H(4)N(2), the crystal packing features π-π stacking inter-actions [centroid-centroid distances = 3.799 (2) and 3.753 (1) Å] as well as N-H⋯(O,O) O-H⋯O and C-H⋯O hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808029231